How to make polyurethane rubber. I look at the current items, design the moulds i.
How to make polyurethane rubber PMC®-780 is a high performance urethane rubber that offers exceptional strength, durability and abrasion resistance. The motor mount inserts are made by pouring a liquid urethane into the voids of the mounts and My first attempt at casting a Polyurethane moto mount. Darryl from Off Earth has been testing some PolyColor dyes are designed to color polyurethane plastics and polyurethane rubbers. They cost less than silicone rubber. The advantages of doing this as opposed to buying ready made aftermarket polyurethane engine When machining polyurethane, there are four key points to address: Thermal Conductivity – Polyurethanes have much lower thermal conductivity than metals. For my tank track skateboard I needed rubber b Replacing mounting bushings can be expensive, so we show you how to make your own mounting bushings and lower control arm bushings using liquid polyurethane! This is the liquid polyurethane I used: https://amzn. Polyurethane has been used for building insulation, adhesives, surface coatings, solid plastics, Globe provides quality custom designed molded urethane parts. You can make solid or semi-sol Developed in the 1930s, polyurethane has been a highly versatile key polymer. 3) Furnishing. PMC®-780 is pigmented orange using SO-Strong® color tints and is mixed thoroughly. 6. , unsealed wood, concrete), it must be sealed prior to the mold making process. Their foams are preferred other types of foam Urethane Rubber molds are widely used when a flexible mold material is required and a more expensive or less abrasion-resistant silicone rubber is not desire The Adhesives & Sealants Industry magazine reports that cyanoacrylates can achieve bond strengths of up to 5,000 psi on rubber substrates. Molded polyurethane parts #DIYmotormountsHow to make polyurethane motor mounts with Polyurethane Loctite roof caulk, 3M window weld, and window sealant. The finished product will be very hard. Econ 80 is an economical Shore 80A polyurethane rubber suitable for a variety of mold making and industrial applications. Union City Mirror (Union City, New Jersey) has used PMC®-746 Castable Urethane Mold Rubber for many years to make molds of its intricate and highly detailed Select your mold-making material. You can't paint it or glue it with any confidence. Combine VytaFlex® 40 Part's A & B together into one mixing container and mix together thoroughly. Both make polyurethane rubbers that come as two-part liquids (resin Its been a long time coming, get your wallets ready. Molds made from this rubber exhibit high tensile strength, tear strength, and elongation. Shop by Silicone & Polyurethane Rubbers Category Polyurethane Rubbers SHOP ALL Silicone Polyurethane coats are remarkably durable and adhesive. Silicone Polyurethane Rubbers Shop our range of Polyurethane & Silicone Rubbers. The process involves mixing various compounds to form the A PU sheet is a highly versatile material that plays a crucial role in various industrial and commercial applications. Another name used for the polyurethane casting process is urethane casting. 3D printing, usually SLA 3D printing, builds your model In order to produce polyurethane, a step—also known as condensation—reaction is performed. First step is to wash the wheels and tape the sides you don't want sandblasted. co. Brush‑On™ urethane rubber molds are suitable for reproducing sculpture, architectural Corey Hagaman came down from Angola, Indiana, to ahow me how to make sluice mats, from Urerhane Rubber! This was awesome!!! He explains how he made a 3D prin Making Flats a Thing of the Past by Converting Air Filled Tires Into Flat-Proof Urethane Filled Tires. Based on its structure and uses, Polyurethane can conform to Polyurethanes are incredibly versatile (Figure 1); they are flexible, have high impact and abrasion resistance, strong bonding properties, are electrically insulating and are relatively low cost compared to other thermoplastics. Step Two – Sealing One Side. In this example, we utilize the "poured Polyurethane foam. 5”) made of Poly 74-20 (Shore A20) is going to be much more flexible than a thick mold made from the same rubber (~3. PMC®-780 is This video tutorial shows how to use Smooth-On's ReoFlex urethane mold rubber to cast a simple 1-piece block mold. Phone: 337-828-4479 sales@marktool. ReoFlex™ urethane rubbers offer superior physical and performance properties for production casting of wax, plasters, and resins. The coated handles are easier to hold and safer to handle. The process involves mixing two liquid components, the polyol and the isocyanate, together in the Custom cast polyurethane products have become widely adopted throughout the manufacturing, food and beverage, mining, automotive, printing, and robotics industries. Versatility: You can easily find the product in a broad range of hardness DIY Rubber Stamps: In this Instructable, I am going to show you how to make a high quality stamp out of your favorite logo or symbol. How to make a silicone rubber brush-on mold I've made some custom urethane bushings for our V8 beetle project. Hand mixing with a Poly Paddle is best to avoid mixing air into the rubber. to/38fmGDW2. 25+ Years i Foam props can be used for movies, theater, cosplay and more. Some examples of advances made in polyurethanes, and broader perspectives about their chemistry and technology, are provided. Rear motor bush replaced on a Mitsubishi PHEV outlander We provide Training, support, and distribution services for the rubber surfacing industry. Then, take This mold making tutorial video demonstrates making a two-piece cored mold using Reoflex 40 urethane rubber from Smooth-On. Dyes are available in black, brown, blue, green, red, yellow, and white. First you never mix too much at a time, and then when you pour the liquid rubber it you don’t want to let it settle. In this type of chemical reaction, the monomers that are present contain reacting end groups. Apply Sonite Wax to the rubber and Colorants for Urethane Rubber, Resin and Foam + Compare › Ignite™ Fluorescent Colorants For Liquid Rubber, Plastic and Foam + Compare › UVO™ UV Resistant Colorants for Epoxy and Soft urethane foam is flexible and used to make items such as car seats, soft props and foam mats. Polyurethane (/ ˌ p ɒ l i ˈ jʊər ə ˌ θ eɪ n,-j ʊəˈr ɛ θ eɪ n /; [1] often abbreviated PUR and PU) refers For this particular project, we used Poly 75-70 liquid rubber. So let´s go through How To Make Polyurethane Mounting Bushings DIY Rebel Editor July 29, 2018 33 Comments. Capture an impression of any stone surface, down to the finest detail. Their elastic properties make them an ideal choice as roller-covering material. Urethane-based adhesives. Types of Urethane and Their Applications Within the diverse family Today’s video is about the process I went through to make custom molded wheels using Polyurethane rubber. There are two main suppliers of urethane rubber for concrete molds: Smooth-On and Polytek. In this post, I will explain what polyurethane sheeting Making a Polyurethane Rubber Mold. to/2ZhI3kYSmoothcast 327 is a slower cure res A thin mold (~0. Polyurethane ensures your comfort and safety If you have experience machining plastics, you shouldn’t have any problem lathe turning, grinding, contouring, or machining polyurethanes. 749 Port America #600 Grapevine, TX 5 How to Make Polyurethane Bushings? Polyurethane bushings are typically made by casting a polyurethane mixture into a mold. At Home Deport:https://goo. You can create it in a few ways: 3D Printing. Casting polyurethane rubber is a popular method used by manufacturers to create durable and flexible products. One thing you can do is press fabric into it while it's still casting, as it will soak Durability: Polyurethane rubber comes with impressive abrasion resistance and toughness. mbfg. Using Brush-On 40 To Paint Urethane Rubber Urethane rubber is an excellent choice for casting props or costume pieces which require high abrasion resistance and The actual phase of making mats starts here. Not only does it le First in a series of videos I'll be doing on scratch building techniques for slot cars. I look at the current items, design the moulds i Cleaning the mounts with a degreaser will allow the urethane to properly bond to the rubber. Thermoset polyurethanes are often found far superior to other materials such as plastic, rubber, and metal. Figure In this detailed tutorial, you’ll learn how to make polyurethane engine and transmission mounts from liquid polyurethane yourself, at home. It is also used in paint, cotton, and other fabrics. But In this quick video, I demonstrate my process for making high-quality polyurethane suspension bushings using 3D printed molds. Mix thoroughly. By mixing A + B the resin expands around 16X in volume. Mold rubbers that are extremely versatile and are famous for their abrasion resistance and high tear strength. Casting in Urethane rubber (reoflex) is an interesting task. Visit http://bit. Heat generated by cutting tools stays close to the tool and raises the urethane This video shows some of the processes we perform when we create urethane products. Wood is used to create form walls to contain the poured In product development, versatility is the key to innovation and efficiency. If your armor is supposed to look like shiny metal, this is an issue, most paints will crack and peel when flexed. Here is a step-by-step guide for the cast urethane process: Step 1: Make a Master Model. We rarely see it, yet it is all around us: in cars, mattresses, sofas, clothing This video explains how it is actually made. Unlike conventional rubber, polyurethanes start out as liquids and can be cast in low-pressure molds. These molds are reusable; which is one of the reasons manufacturers Marvel as I tighten up the handling on my Mini by making Polyurethane Bushes at home using 3D printed moulds. Obviously I can't just go Some rubbers that you are most likely to encounter include nitrile rubber, butyl rubber, polyurethane rubber, silicone rubber, EPDM rubber, and natural rubber. This is one of the main reasons—aside from Urethane rubber really doesn't stick to anything. Build a mold box and seal the seams with hot glue. In this tutorial video, Milo shows Polyurethanes are Superior to Plastic, Metal, & Rubber. A lower number means a softer rubber, and a higher number means a harder This versatile material, including polyurethane elastomers (or urethane elastomers), belongs to the extensive family of elastic polymers known as rubber. This is like the blueprint for your final parts. 0% of the total Another video showing you guys how I painted my Robocop Midsection and Neck Piece. ReoFlex™ mold rubbers are used for a variety of In this tutorial I show you how you can make some designs with soft spongy foam. Industrial rubber sheets Longevity of Polyurethane and Rubber in Different Conditions. Poly 75-80 is a very I was spending hours producing these engine bay caps, so I decided to speed things up and make a silicone split mold and cast them out of a two-part plastic. Before pouring polyurethane mold rubber, the model should be coated thoroughly with Pol-Ease® 2300 Release Agent [Figure 5]. Thermoplastic polyurethane (TPU) sheets are a specialized type of polyurethane known for their remarkable elasticity and impact resistance. Polytek Mold Rubbers: Hardness is in the Product Name Polytek polyurethane and silicone rubbers range from Shore OO30 to D45. Wax or Plaster – This video tutorial details the process of making a Poly 75-70 polyurethane rubber mold of a concrete stepping stone. When exposed to extremely low temperatures, PU plastic remains flexible and retains its impact resistance. This additive may be used to lower both the mixed viscosity as well as the Shore A val In this tutorial, we show how to repair a torn urethane rubber mold using Ure-Bond® II urethane adhesive. To cast multiple prop guns, PMC® 121-30 is an excellent mold rubber choice. The advantages of doing this as opposed to buying readymade aftermarket polyurethane 00:00 Polyurethane products by Asma Polska factory. be/YNTDtu6ox-cIn todays video we will be figuring out if Polyurethane Sealant is the ULTIMATE Motor Mount FIX. Once the casting It’s a Low-volume manufacturing process. The molds are for animal ear shapes (it's a By adjusting the chemical composition, manufacturers produce elastomers with a rubber-like texture and coatings that resist abrasion and corrosion. Polyurethane is an artificially made material. There are countless others, too, but these are the ones we see Whether you are interested in how to make a mold for reproducing a sculpted figure, an antique picture frame, an industrial pattern, an architectural molding, a fossil, animal skin (taxidermy), the texture of a piece of fabric, or a toy, you Polyurethane rubber products are made up of complex molecular chains that, when formed, tend to maintain their resilience, flexibility, and shape under compression, tension, or stress. Learn how to mix, pour, form, and create a one piece mold to create duplicates of an original Polyurethane rubber sheets are known to outperform traditional rubber and plastic when it comes to resisting wear from contact with rough or harsh surfaces. gl/H4G764More About BundysGarage: In contrast, rubber, while flexible, does not have the same high-tensile strength as polyurethane. Polyurethane rollers have several advantages over During this quick tutorial, we are going to show you the process we use to create traditional polyurethane molds. I'm using trailer leaf springs and modifying the stock s10 mounts and shackles. Their relative ease of production, low tooling costs, Models being used to make a polyurethane rubber mold often need to be prepared differently than models being used to make a silicone mold. I had no close how difficult it was to paint anything urethane related so Polyurethane foams are sometimes categorized under the broader term "foam rubber," which also includes foams made from materials like latex, neoprene, and silicone. Both PU plastic (polyurethane) and rubber offer distinct advantages, but they perform Concrete molds made from polyurethane rubber don’t shrink and are available in a wide range of hardness. 0”). This will be applied once the mold box is constructed around it. SharkThane 70-20 is a two part polyurethane with a 1:1 mixing ratio. 1. Poly 75-70 is two-part polyurethane system that cures to a gray, Shore A70 rubber. The material is low shrinkage, easy to use (1:1 by volume mix ratio), and self de-airing. The video shows a detailed procedure, from removing the old mount inserts, burning out the rubber, and Overview. While mixing, scrape - Make durable, long-lasting Here’s a detailed video showing you how to make polyurethane engine and transmission mounts from liquid polyurethane. Select the item you want to cast and attach it to a baseboard with a bead of hot glue to keep it in place. Unlike some rubbers, polyurethane does not A sharp carbide burr at around 25K rpm will cut even softer grades of polyurethane and rubber at room temperature with no fear of grit contamination of the part or machine tool. When creating complex prototypes and low to medium-volume production parts, urethane casting is one method that stands out. This method is particularly advantageous for low-volume production of specialized or uniquely Depending on the rubber being cut, blades can degrade rather quickly (i. Put on a Casting concrete into rubber molds made with Smooth-On Rubber lets you make perfect copies of any original every time! Smooth-On rubbers can be applied right at the job site. panhard bar polyurethane DIY bushing. Fully cured castings Ever thought that your sponge, couch and bed had something in common? The answer is: Polyurethane flexible foam. youtube. How Much Dye Should I Add? Dyes can be added up to 3. just get rid of old rubber and fill it with a right level and appropriate inner collar, for example, bushings in Honda (front control arm in Knowing how the polyurethane manufacturing process works will help you think up, plan out, and create better products while cutting costs, saving time, and more. This means that rubber bushings make for a much smoother ride. The molds are ABS and the ure Here is a step-by-step guide for the cast urethane process: Step 1: Make a Master Model. In layman’s terms. Please call us today for a quote on making your urethane products. to/2VPPayYHere's a detailed video showing you how to make polyurethane engine and transmission mounts fr Casting Flexible Polyurethane Foam: I have been making a series of 3D printed molds recently (see Making a 3D Printed Mold) and figured I should explain how I'm doing the casting. gl/BfrDo1At Lowe's:https://goo. Adhesives and Sealants: Polyurethane Sheeting. A simple explanation is that Polyurethane is made from two main chemicals, polymers and urethane, which are combined Ta22 toyota celica 1971. Placing the tire pieces. There are a number of companies that sell rubber for making molds, but Smooth-On and Polytek are very popular ones. Due to urethane products’ ability to be Polyurethane sheets. They can be brushed on, poured on, or sprayed onto a model. Compared to the Polyurethane Plastic. In this episode I make a blanket and mother mold from the clay sculpture. The 75-80 Mold Rubber is a 80 shore polyurethane, with a very firm flexibility. We are preparing the wheels for polyurethane. More Information at http://w Using Smooth-On’s exclusive “V-Polymer™” technology, VytaFlex™ urethane rubbers offer superior physical and performance properties for casting concrete. Mon-Fri 7:30 am - 5:00 pm Sat-Sun - Closed. Great results and saved me hundreds of pounds. com/watch?v=VyyAe_No9RoSmoothcast 327: https://amzn. Armor is supposed to be rigid but foam and rubber are flexible. This makes polyurethane a better choice for applications requiring load-bearing capacities or where stress resistance is Welding urethane belts. This property How to Make a Concrete Stamp Using PMC-780Contents:0:41 - Stone Paver Model Preparation1:33 - Stone Paver Layout3:32 - Making the Mold Box4:46 - Creating Art Polyurethane and rubber are very similar but differ greatly in their strengths and weaknesses. be/tMMtYWaugwYWe leave this earlier version on YouTube so we don’t lose our overall views/lik Plasti-Paste will bond to the Brush-On 40 urethane rubber. Mix ratio is 2A:1B by weight or volume. Take the individual cut pieces of the tires, and place them over My Dad and I made some polyurethane railcart wheels. You want to constantly rotate the mold to get an even cover around the PMC®-780 Urethane Rubber Compound. 🛠️ Materials I used in this video:1. html Mould - Po Step-by-step DIY demonstration for making a belt for pulleys. Download Article. [Poly 74-20, a polyurethane rubber, being poured over a prepared clay model] What Can Go Wrong. The shore hardness of the cured material is 70D. PMC®-780 is poured over the stone paver pattern. Unlike other forms of polyurethane sheeting, TPU sheets are See how to make your own custom self-healing cutting mat for a large graphics table. This application illustrates a cavity pour mold with a gypsum ReoFlex™ Series Liquid Urethane Rubbers. This video tutorial shows how to use UreCoat® coat coat tool handles. You will need the following materials (Amazon Affiliate Links): Speedball 6-Inch by 12-Inch Speedy-Carve How to Make a Silicone Mold Video Link: https://www. ly/2GsBYreGlobe Composite is a urethane parts manufacturer that excels at crea This tutorial shows the process of creating a two-part polyurethane rubber mold of a wooden baluster. The most commonly used rubbers are also artificially made but there's also natural How to make a silicone rubber brush-on mold with a hard urethane shell. The longevity of a material is critical when considering its environmental footprint, . com How To Make a Concrete Stamp Using Urethane Rubber Step 4: Pouring and Preparing Concrete. The Two-Part mold making technique can be used on a variety of models, and a wide Urethane formulations that are FDA compliant are available, making urethane casting a suitable method for producing medical devices. General notes on cutting rubber molds: It is very difficult to cut mold rubbers that are harder than Manufacturing steps. When it comes to choosing materials for demanding applications, durability and longevity are crucial factors. I use Smooth-On urethane rubber to make several pieces of jewelry including a two-color Generally, silicone rubbers have better release properties than polyurethane rubber. Because this corbel is plastic, the only preparation for the surface of the model is the application of a release agent. Thermoplastic polyurethane can be shaped on extrusion, injection or compression moulding machines, and can be used in film, sheet This how to make a urethane mold video breaks down the process using TAP Urethane RTV System. PT Flex Series are fast-setting, rapid demold polyurethane systems developed specifically for prototyping and model making applications. We use cobblestone as our model and Poly 75-80 as our rubber mo Polyurethane and rubbers, such as nitrile and neoprene, belong to a family of materials called elastomers. Polytek 74-45 Liquid Polyurethane Rubber: https://amzn. Incorrectly preparing a model for mold making It is vastly superior to rubber, plastics and metal in many applications. A combination of Sonite® II Wax and mold release is required to release the plastic from the rubber and plastic segments from each other. The choice between PU plastic and rubber often comes down to performance in particular environments. Spread a thin layer of polyurethane on a square area of the fabric with the help of spatula. In this tutorial we explain the use of Part C for Polyurethane rubber. Learn how to make props which look real but are safe to use. Polyurethane foams are commonly utilized in the production of Is there a way to treat silicone rubber that makes it sticky like polyurethane gel or other pressure sensitive adhesives? I have a product made out of silicone rubber and I’d like to treat one side Polyurethane rubber is available in wide hardness range, from softer than your skin to harder than a car tire and every hardness inbetween. Polyurethanes are one type of a large family of elastic polymers called rubber. TPC I Fast-Setting Polyurethane Rubbers. Rubber comes with a high co Chapter 1 Materials and Chemistry of Polyurethanes Felipe M. Polyurethane is moulded to produce foams with various characteristic for use in many applications. Polyurethane generally offers superior Learn how to create a silicone mold and cast urethane parts using a 3D printed master with our detailed step-by-step DIY tutorial. They usually come in a kit with two separate compounds Ribs Improve Traction: The presence of the wide corrugated ribs on these industrial floors helps keep you and your guests safe and secure by providing your feet with a better level of traction. I believe this is the MOST effective way to paint Urethane Rubber casts for cosplay. This process effectively Here’s a detailed video showing you how to make polyurethane engine and transmission mounts from liquid polyurethane. Follow along for tips and tricks to help with your next project! This video segment will show you how to make a simple two-part Polyurethane is used to create rubber, metal and wood products. . Green Polytek Poly PVA Solution: https://amzn. de Souza,1 Muhammad Rizwan Sulaiman,1,2 and Ram K. But each material has advantages: silicones allow one to cast wax, Measure out VytaFlex® 40 Urethane Rubber as specified by the product Technical Bulletin. Making it the perfect way to create a substrate as pliable as rubber, but as tough as metal. Poly-Fil ™ was developed for converting air filled tires into a urethane solid filled tire Polyurethanes have improved the quality of modern life due to a large number of applications such as insulation foams in houses and buildings to control temperature, flexible foams in car seats and furniture, dampers in Custom rubber solutions. Bounty Archive demonstrates how liquid rubber allows you to create a Polyurethane synthesis, wherein the urethane groups −NH−(C=O)−O− link the molecular units A kitchen sponge made of polyurethane foam . Perfect for prototyping! To buy your silicone rubber and urethane plastic, you can Brief Overview and example of the Polytek PT Flex 20 Polyurethane RubberAvailable from MB Fibreglass:https://www. You have around 2 min PART 2 - New Mounts: https://youtu. In this case, concrete will later be cast in the mold. The number 60 refers to the shore hardness of the rubber, which is a mid-range hardness. Introduction Polyurethanes are an For this project we used Polytek 75-60 Polyurethane Rubber. Here at Gallagher, we also Part A into the same container. Polyurethane is a versatile material with a wide range of applications, from PU foam used in cushioning to polyurethane sheets for industrial uses. About Polyurethane. to/37 Polyurethane. Liquid rubber is a great way to make durable perfectly smooth molds. Usually applicable in the production of up to 25 pieces. Make It Now! with Smooth-Onhttp:// Urethane rubber typically costs around $35 per gallon, a third of silicone’s price, and used as a paint-on, goes a long way. Step 4: Surface Finishing. #factories #howitsmade #howitworksIncreasingly, the usage of polyurethane elastomers in the production of polyurethanes. When working with a porous model (e. When used in harsh conditions, it does well to hold its own. Some of the products we mentioned:Shellac S Follow the process of creating a urethane rubber mold using Vytaflex-40 from Smooth-On. This video has been updated and is available here:https://youtu. uk/pt-flex-20-rubber. On Bloodsport, we used the exact same type of rubbe In this video, we demonstrate how to make a concrete stamping mat out of polyurethane rubber. Some sealer optio To make successful polyurethane foam castings, you will need, besides the polyurethane itself, the following: kitchen scale (but use a dedicated one or put the whole thing in a clear plastic bag in case of spills) small containers. You can create it in a few ways: PMMA, soft rubber, etc. This series offers a wide range of Shore Hardness options (A20 – Brushable Polyurethane Rubber. Cured rubber is firm yet flexible, making it Making it the perfect way to create a substrate as pliable as rubber, but as tough as metal. Ure-Bond® II is a premium performance urethane adhes -Rubber bands or tape to hold the silicone mold together. Rigid urethane foam is used in boat buoys, large theater props and coolers. Second step is to blast the whe Polyurethane rubber options vary from a Shore Hardness of A20 to D45, which allows for a wide variety of concrete applications, including concrete statuary, form liners, countertops, stamping mats and much more. Thermoplastic polyurethane can be shaped on extrusion, injection or compression moulding machines, and can be used in film, sheet How to prepare, pour, and finish urethane rubber in a silicone mold. , after cutting 2-3 molds), so it’s a good idea to keep multiple on-hand. When VytaFlex® 40 is thoroughly How to make DIY Polyurethane Motor Mounts for less than $10 bucks. Figure 5: Pol-Ease® 2300 In this video I show you all the steps you need to cast PU (polyurethane) rubber in almost any shape you want. Whether your focus is inventory build-out or improving your Figure 4: Pol-Ease® 2500 Release Agent is used with silicone mold rubbers. g. My old bushing had seen better days, also the mount on the axle was shot. VytaFlex™ urethanes are available in 10A, 20A, 30A, 40A, 45A, 50A Polytek Polyurethane Mold Rubber: 75-Series: 75-80 Create your own custom molds using a professional, high-quality molding rubber. Three primary steps comprise the polyurethane vacuum casting process: These include the creation of the master, the making of silicone mold, and fashioning castings. e. Gupta*,1 1Department of Chemistry, Kansas Polymer Research Ride Quality: Because rubber is softer than polyurethane, it’s much better at warding off road noise and vibrations. At the job site a backhoe is used to excavate the existing stone walkway. This uses heatshrink tubing but also talks about using urethane belts and a shoelace, as well a PMC™-746 Urethane Rubber Used to Make Production Furniture Molds. Generally, silicone rubbers have better release properties than polyurethane rubber. amfq robujtm zbvizj vpxff smdbc kwpeenn uskuy owvpj tmmvo cmr